]>

Table 3: Eutectic composition and phase transition temperatures (°C) of group B ternary mixtures.

4–CnH2n+1O–C6H4–COO–C6H4–OOC–C6H4–X–4 System $n$ Composition (mol%) ${\mathbf{T}}_{\text{C–N}}$ ${\mathbf{T}}_{\text{N–I}}$ ${\mathbf{T}}_{\text{N–I}}$ A/B/C A B C (found) (calc.) $\mathbf{I}{6}_{\text{a}}/\mathbf{I}{6}_{\text{c}}/\mathbf{I}{6}_{\text{d}}$ 6 48.0 25.5 26.5 90.1 247.2 246.7 $\mathbf{I}{6}_{\text{a}}/\mathbf{I}{6}_{\text{c}}/\mathbf{I}{6}_{\text{e}}$ 58.6 31.4 10.0 92.5 234.0 239.5 $\mathbf{I}{6}_{\text{a}}/\mathbf{I}{6}_{\text{d}}/\mathbf{I}{6}_{\text{e}}$ 58.2 31.8 10.0 81.5 247.2 252.2 $\mathbf{I}{6}_{\text{b}}/\mathbf{I}{6}_{\text{c}}/\mathbf{I}{6}_{\text{d}}$ 61.0 21.0 18.0 86.3 227.0 230.3 $\mathbf{I}{6}_{\text{b}}/\mathbf{I}{6}_{\text{c}}/\mathbf{I}{6}_{\text{e}}$ 63.6 18.6 17.8 95.0 226.0 227.1 $\mathbf{I}{6}_{\text{b}}/\mathbf{I}{6}_{\text{d}}/\mathbf{I}{6}_{\text{e}}$ 63.5 18.5 18.0 86.3 232.5 234.5 $\mathbf{I}{8}_{\text{a}}/\mathbf{I}{8}_{\text{c}}/\mathbf{I}{8}_{\text{d}}$ 8 54.5 24.5 21.0 99.4 229.5 227.8 $\mathbf{I}{8}_{\text{a}}/\mathbf{I}{8}_{\text{c}}/\mathbf{I}{8}_{\text{e}}$ 53.0 24.0 23.0 94.1 227.5 224.8 $\mathbf{I}{8}_{\text{a}}/\mathbf{I}{8}_{\text{d}}/\mathbf{I}{8}_{\text{e}}$ 61.0 24.5 14.5 99.2 237.0 233.4 $\mathbf{I}{8}_{\text{b}}/\mathbf{I}{8}_{\text{c}}/\mathbf{I}{8}_{\text{d}}$ 67.8 17.2 15.0 80.5 214.0 210.5 $\mathbf{I}{8}_{\text{b}}/\mathbf{I}{8}_{\text{c}}/\mathbf{I}{8}_{\text{e}}$ 71.0 18.0 11.0 78.3 210.5 206.7 $\mathbf{I}{8}_{\text{b}}/\mathbf{I}{8}_{\text{d}}/\mathbf{I}{8}_{\text{e}}$ 73.8 16.2 10.0 75.3 217.0 212.6 $\mathbf{I}{14}_{\text{a}}/\mathbf{I}{14}_{\text{c}}/\mathbf{I}{14}_{\text{d}}$ 14 46.0 34.5 19.5 88.4 194.2 198.2 $\mathbf{I}{14}_{\text{a}}/\mathbf{I}{14}_{\text{c}}/\mathbf{I}{14}_{\text{e}}$ 52.0 37.0 11.0 86.0 195.1 192.9 $\mathbf{I}{14}_{\text{a}}/\mathbf{I}{14}_{\text{d}}/\mathbf{I}{14}_{\text{e}}$ 61.5 26.0 12.5 82.5 192.2 206.2 $\mathbf{I}{14}_{\text{b}}/\mathbf{I}{14}_{\text{c}}/\mathbf{I}{14}_{\text{d}}$ 63.0 23.1 13.9 88.0 186.0 180.6 $\mathbf{I}{14}_{\text{b}}/\mathbf{I}{14}_{\text{c}}/\mathbf{I}{14}_{\text{e}}$ 62.8 22.6 14.6 75.5 182.0 178.3 $\mathbf{I}{14}_{\text{b}}/\mathbf{I}{14}_{\text{d}}/\mathbf{I}{14}_{\text{e}}$ 67.6 16.0 16.4 86.0 192.0 185.4